With water cooling, you are reliant on every part in the system working as it should, in order to have a functional cooling system. The blocks need to not clog, the radiators need to not leak, the fittings need to remain watertight, and the pump needs to remain powered. If any one of these things fail, you generally have a big problem pretty quick (overheating).
AIO rearranged per Gamers Nexus's recommendation : r/NZXT
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